OCCUPATIONAL HEALTH SERVICES INC -- FERROUS CHLORIDE -- 6810-00F032000
===================== Product Identification ===================== Product ID:FERROUS CHLORIDE MSDS Date:12/27/1989 FSC:6810 NIIN:00F032000 === Responsible Party === Company Name:OCCUPATIONAL HEALTH SERVICES INC Address:450 7TH AVE SUITE 2407 City:NEW YORK State:NY ZIP:10123 Country:US Info Phone Num:212-967-1100/800-445-MSDS Emergency Phone Num:615-292-1180/212-967-3973 Preparer's Name:JOHN S BRANSFORD JR CAGE:0G772 === Contractor Identification === Company Name:OCCUPATIONAL HEALTH SERVICES INC Address:450 7TH AVE SUITE 2407 Box:City:NEW YORK State:NY ZIP:10123 Country:US Phone:212-967-1100/800-445-MSDS CAGE:0G772 ============= Composition/Information on Ingredients ============= Ingred Name:FERROUS CHLORIDE CAS:7758-94-3 RTECS #:NO5400000 Fraction by Wt: 100% ACGIH TLV:1 MG/CUM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 984 MG/KG TETRAHYDRATE Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CORROSIVE. INHALATION: DIFFICULT BREATHING & IRRITATION OF MUCOUS MEMBRANES. SKIN: IRRITATION, BURNS; POISONING MAY OCCUR THROUGH ABSORPTION, DERMATITIS. EYES: IRRITATION. INGESTION: SEVERE GASTRITIS/ GASTROENTERITIS, LEUKOCYTOSIS, CYANOSIS, CARDIOVASCULAR COLLAPSE, FATAL, LIVER/KIDNEY/PANCREAS DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: INFLAMMATION, LOCAL BROWN DISCOLORATION. INGESTION: NAUSEA, VOMITING, DEHYDRATION, FEVER, RESTLESSNESS, LETHARGY, HYPOTONIA, COMA, FAST-WEAK PULSE, HYPOTENSION, HYPERVENTILATION, SHOCK, VASOMOTO R INSTABILITY, CONVULSIONS, DEATH. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. GIVE CPR OR OXYGEN AS NECESSARY. KEEP WARM/AT REST. TREAT SYMPTOMATICALLY/SUPPORTIVELY. ADMINISTRATION OF OXYGEN SHOULD BE PERFORMED BY QUALIFIED PERSONNEL. SKIN: WAS H W/SOAP/MILD DETERGENT & WATER FOR 20 MINS. IF BURNED, USE STERILE DRESSING. EYES: WASH W/WATER FOR 20 MINS. INGESTION: INDUCE VOMITING W/SYRUP OF IPECAC, THEN GASTRIC LAVAGE. OBTAIN MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CO2, HALON, WATER SPRAY, FOAM, FOG Fire Fighting Procedures:MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE. COOL COTNAINERS W/WATER FROM SIDE, WELL AFTER FIRE IS OUT. STAY AWAY FROM STORAGE TANK ENDS. Unusual Fire/Explosion Hazard:DON'T USE WATER DIRECTLY ON MATERIAL. IF LARGE AMOUNTS OF COMBUSTIBLE MATERIALS ARE INVOLVED, USE WATER SPRAY/FOG IN FLOODING AMOUNTS. KEEP UPWIND. ================== Accidental Release Measures ================== Spill Release Procedures:SOIL: DIG PIT TO CONTAIN. WATER: NEUTRALIZE. ALLOW TO AERATE. DON'T TOUCH MATERIAL. SMALL SPILL: ABSORB W/SAND & PUT IN CONTAINERS. LARGE SPILL: DIKE AREA. EVACUATE AREA. REPORTABLE QUANTITY: 100 LBS. Neutralizing Agent:AGRICULTURAL LIME, SLAKED LIME, CRUSHED LIMESTONE, SODIUM BICARBONATE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES IN TIGHTLY CLOSED CONTAINERS. Other Precautions:POISONOUS GASES MAY ACCUMULATE IN TANKS & HOPPER CARS. MAY IGNITE COMBUSTIBLES (WOOD, PAPER, OIL). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST & MIST, AIR PURIFYING W/HIGH EFFICIENCY PARTICULATE FILTER, AIR SUPPLIED, SCBA. ALL MUST BE USED W/TIGHT FITTING FULL FACEPIECE MASK IN POSITIVE PRESSURE MODE. Ventilation:LOCAL EXHAUST, GENERAL DILUTION Protective Gloves:IMPERVIOUS Eye Protection:SPLASH & DUST PROOF FACE SHIELD/GOGGLES Other Protective Equipment:IMPERVIOUS CLOTHING, EYE WASH & SHOWER Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING & SHOES IMMEDIATELY. Supplemental Safety and Health MAY AFFECT CARDIOVASCULAR & CENTRAL NERVOUS SYSTEMS, LIVER, KIDNEY, AND PANCREAS. PH: ACIDIC IN SOLUTION. PRODUCT IS SOLUBLE IN ALCOHOL & ALCOHOL; SLIGHTLY SOLUBLE IN BENZEN; PRACTICALLY IN SOLUBLE IN ETHER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:1873F Melt/Freeze Pt:M.P/F.P Text:1238-1245F Vapor Pres:10 Spec Gravity:3.16 pH:SUPP Solubility in Water:APPRECIABLE Appearance and Odor:GREENISH-WHITE-YELLOW DELIQUESCENT CRYSTALS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI METALS: HAZARDOUS REACTION. ETHYLENE OXIDE: EXOTHERMIC POLYMERIZATION. POTASSIUM & SODIUM: VIOLENT EXPLOSION. Stability Condition to Avoid:FIRE & OTHER IGNITION SOURCES Hazardous Decomposition Products:OZONIDES: EXPLOSIVE DECOMPOSITION. TOXIC & CORROSIVE FUMES OF CHLORIDES. Conditions to Avoid Polymerization:ETHYLENE OXIDE: MAY CATALYZE EXOTHERMIC POLYMERIZATION ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.