DUPONT E I DE NEMOURS & CO PETROCHEMICALS DEPT -- FREON -- 4935-00-930-3892
===================== Product Identification ===================== Product ID:FREON MSDS Date:05/01/1989 FSC:4935 NIIN:00-930-3892 Status Code:A === Responsible Party === Company Name:DUPONT E I DE NEMOURS & CO PETROCHEMICALS DEPT Address:FREON PRODUCTS DIVISION City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-9450 Emergency Phone Num:800-441-3637-MED,800-424-9300-TRAN Preparer's Name:KP BROWN CAGE:23027 === Contractor Identification === Company Name:E I DUPONT DE NEMOURS & CO, FREON PROD (REPLACED BY 73925) Address:1007 MARKET ST Box:City:WILMINGTON State:DE ZIP:19899 Country:US Phone:800-441-3637-MED 800-424-9300-TRAN CAGE:5P414 Company Name:PACIFIC SCIENTIFIC CO HTL/KIN-TECH DIVISION Address:1800 HIGHLAND AVE Box:City:DUARTE State:CA ZIP:91010 Country:US Phone:818-359-9317/602-796-1100 CAGE:05167 Company Name:TETRA MFG CORP (CAGE CANCELLED) Address:CAGE CANCELLED City:WESTBURY State:NY ZIP:11590 Country:US Phone:NONE CAGE:23027 ============= Composition/Information on Ingredients ============= Ingred Name:TRIFLUOROMETHANE (FREON 23).LC50 SPECIES UNKNOWN INHALATION >900,000 PPM/HOUR. CAS:75-46-7 RTECS #:PB6900000 Fraction by Wt: 84% Other REC Limits:1000 PPM (MFR) OSHA PEL:NOT KNOWN ACGIH TLV:NOT KNOWN Ingred Name:TETRAFLUOROMETHANE (FREON 14).ALC RAT INHALATION 895,000 PPM/15 MINUTES. CAS:75-73-0 RTECS #:FG4920000 Fraction by Wt: 16% Other REC Limits:NOT KNOWN OSHA PEL:NOT KNOWN ACGIH TLV:NOT KNOWN ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT KNOWN Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION OF HIGH CONCENTRATIONS OF VAPOR MAY CAUSE DEATH.INTENTIONAL MISUSE CAN BE FATAL. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES/SKIN:LIQUID CONTACT CAN CAUSE FROSTBITE. INHAL:VAPOR REDUCES OXYGEN AVAIL FOR BREATHING.EFFECTS MAY INCLUDE TEMPORARY CNS DEPRESSION W/ NAUSEA,WEAKNESS,DIZZINESS,HEADACHE,CONFUSION,INCOORD,UNCON. EXPOSURE TO >20%:POSS TEMPORARY ALTERATION OF HEART'S ELEC ACTIVITY W/ IRREGULAR PULSE,PALPITATIONS,INADEQ CIRCULATION. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH W/ LOTS OF WATER FOR AT LEAST 15 MINUTES.CALL MD. SKIN:FLUSH W/ WATER.TREAT FOR FROSTBITE IF NEEDED. INHALATION:IMMEDIATELY REMOVE TO FRESH AIR.KEEP PERSON CALM.IF NOT BREATHING ,GIVE ARTIFICIAL RESPIRATION.IF BREATHING IS DIFFICULT,GIVE OXYGEN.CALL MD. NOTE TO MD:USE CATECHOLAMINE DRUGS (EPINEPHRINE) W/ SPECIAL CAUTION IN LIFE SUPPORT DUE TO POSS CARDIAC RHYTHM DISTURBANCES. ===================== Fire Fighting Measures ===================== Flash Point:NOT KNOWN Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS (SCBA) IS REQUIRED IF CYLINDERS RUPTURE OR RELEASE UNDER FIRE CONDITIONS. Unusual Fire/Explosion Hazard:COOL CONTRS W/ WATER SPRAY OR FOG.CYLINDERS ARE EQUIPPED W/ PRESS & TEMP RELIEF DEVICES,BUT STILL MAY RUPTURE IN FIRE CNDTNS.AUTODECOMPOSITION TEMP:>765C,1409F. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA-ESPECIALLY LOW PLACES WHERE HEAVY VAPORS MIGHT COLLECT.REMOVE OPEN FLAMES.WEAR SELF-CONTAINED BREATHING APPARATUS FOR LARGE SPILLS. Neutralizing Agent:NOT KNOWN ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLEAN,DRY AREA.DO NOT HEAT ABOVE 123F,50.5C. Other Precautions:AVOID BREATHING VAPORS AND PROLONGED SKIN EXPOSURE.USE WITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE EXPOSURE BELOW RECOMMENDED LIMITS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNDER NORMAL USE CONDITIONS,NO RESPIRATORY EQUIPMENT IS REQUIRED.USE SELF-CONTAINED BREATHING APPARATUS IF A LARGE SPILL OR RELEASE OCCURS. Ventilation:STANDARD PROCEDURES:NORMAL VENT IS GENERALLY ADEQUATE.LARGE RELEASE:USE LOCAL EXHAUST.USE MECHANICAL VENT IN LOW PLACES. Protective Gloves:LINED LEATHER GLOVES. Eye Protection:CHEMICAL SPLASH GOGGLES. Other Protective Equipment:NOT KNOWN Work Hygienic Practices:NOT KNOWN Supplemental Safety and Health SPECIFIC GRAVITY:1.413 AT -80C,-112F (WATER=1).VAPOR PRESSURE:119 PSIA AT -51C,-60F. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-146F,-99C Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN Decomp Temp:Decomp Text:NOT KNOWN Vapor Pres:SEE SUPP Vapor Density:2.52,AIR=1 Spec Gravity:SEE SUPP DATA Evaporation Rate & Reference:>1 (CCL*4=1) Solubility in Water:0.08% BY WEIGHT Appearance and Odor:CLEAR,COLORLESS GAS W/ SLIGHT ETHEREAL ODOR.PROD IS COMPRESSED GAS IN CYLINDER. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS-POWDERED ALUMINUM,ZINC,BERYLLIUM,ETC. Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES. Hazardous Decomposition Products:DECOMPOSED BY HIGH TEMP (OPEN FLAMES,GLOWING METAL SURFACES,ETC) FORMING HYDROFLUORIC ACID & POSSIBLY CARBONYL HALIDES. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE,AND LOCAL REGULATIONS.COORDINATE WITH SUPPORTING INSTALLATION AND/OR MACOM ENVIRONMENTAL OFFICE PRIOR TO DISPOSAL .RECLAIM BY DISTILLATION OR VE NT TO ATMOSPHERE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.