ASHLAND PETROLEUM CO DIV OF ASHLAND OIL INC -- GASOLINE UNLEADED -- 9130-00-264-4538
===================== Product Identification ===================== Product ID:GASOLINE UNLEADED MSDS Date:05/31/1989 FSC:9130 NIIN:00-264-4538 === Responsible Party === Company Name:ASHLAND PETROLEUM CO DIV OF ASHLAND OIL INC Address:1409 WINCHESTER AVE Box:391 City:ASHLAND State:KY ZIP:41114 Country:US Info Phone Num:606-329-3333 Emergency Phone Num:800-274-5263 CAGE:81355 === Contractor Identification === Company Name:ASHLAND INC Address:1409 WINCHESTER AVE Box:391 City:ASHLAND State:KY ZIP:41114 Country:US Phone:800-622-6846 CAGE:81355 ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: >95% Other REC Limits:NONE SPECIFIED BY M. OSHA PEL:300 PPM/500 STEL ACGIH TLV:300 PPM/500STEL;9192 Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 1-5% OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 3-7% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 3.8-9.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:P-XYLENE (P-DIMETHYLBENZENE) (SARA III) CAS:106-42-3 RTECS #:ZE2625000 Fraction by Wt: 0.8-2.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 1-4% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE-INHALATION:CNS DEPRESSION, IRRITATION OF RESPIRATORY TRACT. EYE:IRRITATION. SKIN:IRRITATION. INGESTION:GI DISTURBANCES, ASPIRATION PNEUMONITIS. CHRONIC:DERMATITIS, PNEUMONITIS, PULMONARY EDEMA, ANEMIA, LIVER & KIDNEY DAMAGE. Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:EYE:SEVERE IRITATION, REDNESS, TEARING, BLURRED VISION; SKIN:IRRITATION, DEFATTING, DERMATITIS; INHALE: NASAL AND RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIQUE, NAUSEA, ETC.; INGEST: GASTROINTE STINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/OXYGEN IF NEEDED. EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL HELP. SKIN CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS PERSIS T. INGESTION:DO NOT INDUCE VOMITING, DRINK 1-2 GLASSES OF WATER. GET MEDICAL HELP IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-40F/-40C Lower Limits:1.5 Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES. Unusual Fire/Explosion Hazard:MATERIAL IS HIGHLY VOLATILE & READILY GIVES OFF VAPORS WHICH MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION & IGNITED BY PILOT LIGHTS, SPARKS, ETC. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL: ELEMINATE ALL SOURCES OF IGNITION AND ABSORB LIQUID ON VERMICULITE, INERT ABSORBENT, ETC, AND TRANSFER TO HOOD. LARGE SPILL: ELEMINATE IGNITION SOURCES. DIKE AREA TO CONTAIN. PUMP LIQUID TO SALVAGE TANK FOR LATER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE OR STORE ONLY WITH ADEQUATE VENTILATION. Other Precautions:DO NOT TRANSFER TO UNLABELED CONTAINERS. DO NOT USE CUTTING OR WELDING TORCH ON THIS CONTAINER. KEEP OUT OF REACH OF THE CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH APPROVED AIR SUPPLIED RESPIRATOR IF TLV IS EXCEEDED. Ventilation:PROVIDE SUFFICIENT MECHANICAL VENTILATION AND/OR LOCAL EXHAUST TO KEEP BELOW TLV. Protective Gloves:NEOPRENE, NITRILE, RUBBER TYPES. Eye Protection:CHEMICAL SPLASH GOGGLES. Other Protective Equipment:CLOTHING AND BOOTS. Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE WHILE WORKING WITH THIS PRODUCT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:70F/21C Vapor Pres:325 MMHG Spec Gravity:0.74 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:CLEAR LIQUID, GASOLINE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECLAIM, INCENERATE OR DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.